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V:YAG Passive Q-switching Crystal

V:YAG Passive Q-switching Crystal photo-1
V:YAG Passive Q-switching Crystal photo-2

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Vanadium-doped yttrium aluminum garnet crystal is abbreviated as V:YAG crystal, with the chemical formula V:Y₃Al₅O₁₂. It is a novel saturable absorber material, suitable for passive Q-switching of lasers operating in the wavelength range of 1.0–1.5 μm, and exhibits outstanding advantages especially
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                                                                               Introduction

                Vanadium-doped yttrium aluminum garnet crystal is abbreviated as V:YAG crystal, with the chemical 

formula V:Y₃Al₅O₁₂. It is a novel saturable absorber material suitable for passive Q-switching of lasers in the wavelength range of 1.0–1.5 μm, and presents particularly prominent advantages for 1.3 μm neodymium (Nd) lasers.

High Ground State Absorption (GSA) Cross-section

               Near 1.3 μm, the ground state absorption (GSA) cross-section of V³⁺:YAG reaches as high as \(7\times10^{-18}\ \

mathrm{cm^2}\), which is significantly higher than that of traditional materials such as Cr⁴⁺:YAG. It can efficiently 

absorb laser energy and trigger the Q-switching process.

Extremely Low Excited State Absorption (ESA)

            The excited state absorption is negligible, enabling a Q-switching contrast ratio (ratio of initial small-signal 

absorption to saturated absorption) exceeding 10. This ensures high-contrast pulse modulation and eliminates 

interference from continuous laser background.

Broad Wavelength Adaptability

            It is applicable to 1.3 μm and 1.44 μm Nd-doped lasers. Efficient Q-switching can be realized without 

intracavity focusing, compatible with both flash lamp pumping and laser diode pumping.

Excellent Crystal Performance

              The YAG host crystal features outstanding optical, mechanical and thermal stability, laying a foundation

 for designing compact and high-reliability lasers, and is especially suitable for miniaturized and high-power 

application scenarios.

Application Potential

             Compared with Semiconductor Saturable Absorber Mirrors (SESAM), bulk V³⁺:YAG crystal possesses higher

 damage threshold and lower insertion loss, making it a preferred candidate material for passive Q-switching in 

the 1.3 μm waveband.

Summary

               With high absorption cross-section, low excited state loss and superior physical properties, V³⁺:YAG provides

 an innovative solution for the miniaturization and high-power pulse output of 1.3 μm lasers. It has broad application prospects in industrial, medical and scientific research laser fields in the future.


Material Properties

Parameter Specification
Chemical Formula V:Y₃Al₅O₁₂
Doping Concentration 0.1~5 at%
Growth Direction [100] or [111]
Crystal Structure Cubic Crystal System
Lattice Parameter 1.201 nm
Density 4.55 g/cm³
Melting Point 1970°C
Refractive Index @1.34 μm n=1.81
Mohs Hardness 8.0
Applicable Wavelength Range 1–1.5 μm
Absorption Cross-section \(\sim7\times10^{-18}\ \mathrm{cm^2}@1.34\ \mu\mathrm{m}\); \(\sim3\times10^{-18}\ \mathrm{cm^2}@1.06\ \mu\mathrm{m}\)
Relaxation Time 20–30 ns


Standard Products & Processing Specifications

Parameter Technical Index
Dimension W(3×3)~H(10×10)×L(0.5–8) mm³ or customized
Initial Transmittance (%) 40–95%
Absorption Coefficient @1.34 μm (cm⁻¹) 0.1–2.5
Parallelism 30 arcsec
Perpendicularity 15 arcmin
Surface Quality 10-5
Flatness λ/8
Wavefront Distortion λ/4
Effective Aperture 90%
Edge Chipping < 0.1 mm
Chamfer < 0.1 mm×45°


详情页

Product Tags: V:YAG , Q-switching crystal

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